Your comment about "scavenging losses" (if I understand you correctly) applies more to the "wasted volume" between the valve seat and the base of the pellet, which in Lloyd's spreadsheet we call the "Transfer Port Volume".... That volume should be kept as small as possible, because the air in the reservoir/plenum must expand to fill it before the pellet sees any pressure to start it on it's journey....
looks incredible Bob..cant wait to see some long range results.
I hope the above examples help you to understand why larger plenum volumes increase the efficiency, because they have less pressure drop during the shot.... and also why dump valves are not used in PCPs, because they are so inefficient....