Bye bye stem ... compression loading is IMO going to pretzel it in short order if not the snapping shut of the valve going the other way does not break it first.JMO ... as you were
If you did a hybrid type stem using say .040 to.063" tempered spring steel that went into the PEEK poppet head, but also bonded into the more typical 1/8" stem threw the body it likely would survive without fatigue.* In other words the reduced diameter is precision ground and flexible spring steel where the reduced diameter within throat is at, full diameter threw body to hammer struck end.Just thinkin out loud
I would suggest using a Cothran valve if you can get one. I did all the tricks with PEEK poppets, yes they work but the numbers will always be severely restricted by the fact that the seat is so close to the exhaust on the stock valves that you are limited in what can be done with the stock valve. In the long run, it's just simply not worth the time to tweak one and stay within the limitations. I probably went through 4 stock valves modding them and porting, even moved the seat forward in one using stainless tubing set in JB weld. It worked, but nowhere nearly as good as the Cothran.By the time I quit wasting efforts on the stock valve, I had spent over $100 on them, and had enough time invested in my efforts to buy ten Cothran valves if I paid myself $5/hr.
My last 36" piece of 5/16" O.D. natural PEEK came out of Interstate plastics here in Sacramento
I wonder how a coned shaped plug poppet would do instead of the traditional flat stopper style configuration when making one with a larger OD.