Please, no talk of shooting primers. This has been discussed on several forums and is, basically, dangerous. Primers can be dangerous to handle and fragment if exploded outside of the cartridge/gun they are intended for. Inside most primers is a little piece of metal called an anvil that the firing pin strikes to ignite the priming compound. In an unsupported primer, the anvil has been known to blow back.These gizmos do not turn a firearm into an air rifle since they don't use air to propel the pellet. They are closer to .22 CB cartridges.
I wouldn't think the lead pellet would lead up a .22 barrel any more than a lead .22lr round. I don't know that you could really call it a powder burner either, as what is in a primer isn't really powder. Gun powder doesn't go off if you smack it hard (what the firing pin does to the primer), whats in the primer is some compound that explodes when smashed. I'm not a chemist, so I can't say what is in there. I do know that at some point primers contained mercury, as they sometimes throw in mercury free primers in the advertising.....