I'm not sure about the peek they're using for printing but back when I worked for a aerospace composites manufacturer peek was some dangerous stuff at high temps where it cured at. I know around the time I was layed off that the R&D Chemist were close to making it non toxic.
Okay guys, my sometimers got me on this. It wasn't peek that was dangerous it was polyamide that was the dangerous one. If I had just stopped and thought a little more I would have remembered that peek is a thermal plastic and polyamide is a thermal set as in you can't 3d print with a thermal set. Sorry 😲